A case study on indirect coal liquefaction process. 2 Fantoni and Bonaccorsi, 2017; Chiarello et al., 2019; Fantoni et al., 2021), we have developed a novel knowledge graph (KG) (Sidor, 2015) with HAZOP as the carrier for industrial safety through bridging data science and engineering design, named
Coal liquefaction residue is the solid waste from the liquefaction system and accounts for about 2530% of the feed. 4 Thermal conversion through gasification is a better way to deal with this residue, which is of great significance in economical efficiency. 5 It should be noted that ironbased catalysts are widely used in coal liquefaction, as ...
Typical liquefaction process is performed at 400 °C for 60 min under 5 MPa H 2 (initial pressure) in 2:1 (solvent: coal) tetralin solvent with 5% FeS + S (an equimolar mixture of FeS and S) as catalyst. A detailed procedure of hydroliquefaction and separation can be seen elsewhere [31]. The AS and PA obtained by a batch liquefaction were ...
The effective utilization of the coal liquefaction residue (CLR), which contains about 80% organic matter, is of great significancefor improving the oil yield of the direct liquefaction...
The Bergius process is a method of production of liquid hydrocarbons for use as synthetic fuel by hydrogenation of highvolatile bituminous coal at high temperature and pressure. It was first developed by Friedrich Bergius in 1913. In 1931 Bergius was awarded the Nobel Prize in Chemistry for his development of highpressure chemistry.
1. Introduction. Direct coal liquefaction is the technology of catalytic converting coal to clean liquid fuel through hydrocracking the polycyclic aromatic hydrocarbons in coal to small aliphatic molecules [1].It can effectively reduce the emission of industrial waste and toxic gases as well as improving the coal utilization, thereby, showing great potential for sustainable development of coal ...
The fuels considered include high and low sulfur bituminous coals, lignite, anthracite, the products of various coal gasification, liquefaction, and solvent refining processes, coal loaded with ...
Summary Coal liquefaction is an industrial process in which coal as raw material, through chemical reactions, is converted into liquid hydrocarbon mixture, which, under further processing, becomes desired liquid fuels or chemical feedstock.
Direct Coal Liquefaction Process Makeup Hydrogen Coal + Catalyst Recycle H 2 Gas Recovery Treatment Coal Liquefaction HDonor Slurry Slurry Hydro treating Fractionation DeAshed Solvent Deashing Oil (DAO) Refining H 2S, NH 3, CO x C C 2 LPG Gasoline Diesel Fuel Heavy Vacuum Gas Oil (HVGO) Ash Reject Direct Coal Liquefaction Plants
A twostage direct liquefaction process is designed to give distillate products via two reactor stages in series. The primary function of the first stage is coal dissolution and is operated either without a catalyst or with only a lowactivity disposable catalyst. The heavy coal liquids produced in this way are hydrotreated in the second stage ...
Coal resources have been used to produce liquid transportation fuels by several process routes collectively referred to as coal liquefaction or, more generally stated, as coal to liquids (CTL). Early records of coal conversion to liquid fuel date to 1913 and an extraction process developed by Friedrich Bergius in Germany [ 7 ].
Much of the research and process development on coal liquefaction after the 1990s was aimed at matching the fuels synthesis conditions with modern, efficient coal gasifiers such as those developed by Uhde, Texaco (now GE), Shell, and CBI. ... (1999) (PDF). Technology status report 010: coal liquefaction. Department of Trade and Industry. http ...
All direct coal liquefaction methods, such as HCoal, SolventRefined Coal, and Exxon Donor Solvent processes, are alike in one principal point: coal is thermally solubilized with certain solvents, usually coalderived, with or without catalysts. If heated in a proper liquid for a short time, most of the coal dissolves.
At the beginning of the 20th century the direct liquefaction process was first done by reacting coal with hydrogen and process solvent at high temperatures and pressure to produce liquid fuels. This direct liquefaction process was used to produce high octane aviation gasoline by Germany during World War II. The Fischer Tropsch technology
In NEDOL's 1tonperday process supporting unit, a plant designed to provide support data for the NEDOL coal liquefaction process which has been developed up to the 150tonsperday scale, the ...
The purpose of coal conversion is the production of alternative fuels, including motor fuels, or the generation of a range of chemicals from coal by process routes, such as gasification, direct and indirect liquefaction, hydropyrolysis, and plasmapyrolysis. The application of these techniques is essential if the large reserves of coal are to be ...
Bergius treated a mixture of pulverized bituminous coal and coalderived heavy oil with hydrogen, at high temperature and pressure, to give a liquid product consisting of heavy oils, middle distillates, gasoline, and gases. Various metal compounds have been used to catalyze the process.
water, boiler feed water, and cooling water. Process water is used in the liquefaction process and often plays a part in chemical reactions. Boiler feed water is used to produce steam, and much of it is recovered and returned to the boiler. Cooling is typically done using circulating water. Cooling water loss is often the most significant factor.
Direct coal liquefaction (DCL) The conversion of coal to liquids via dissolution and/or hydroprocessing, without first gasifying the coal DOE United States Department of Energy FischerTropsch reaction The catalytic conversion of synthesis gas to primarily hydrocarbons, the discovery being credited to Franz Fischer and Hans Tropsch
Indirect coal liquefaction necessitates first coal gasification, followed by Fischer Tropsch (FT) fuel synthesis. ... As per our results, the indirect liquefaction process has a higher conversion rate (4045 %) than other modern coal chemical processes (3540 % for coaltoolefin, 4048 % for coaltomethanol, and 3845 % for IGCC ...
However, similar to other coal liquefaction processes, the DCL process has not been widely commercialized mainly because of economic uncertainty, high CO 2 emission, and high capital cost [1,2].
Coal liquefaction is one source, backed by large recoverable coal reserves globally. Significant coal liquefaction research and development (RD) was started up in the early 1970s, particularly in the USA, the UK and Japan, in response to various oil price shocks.
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