The Bergius process is a method of production of liquid hydrocarbons for use as synthetic fuel by hydrogenation of highvolatile bituminous coal at high temperature and pressure. It was first developed by Friedrich Bergius in 1913. In 1931 Bergius was awarded the Nobel Prize in Chemistry for his development of highpressure chemistry.
H5 Significant fluctuations in the light oil yield obtained from laboratory and pilot scale models of heavy oil upgrading. coal/oil coprocessing and direct coal liquefaction processes. arising ...
In the discussion above the fuels synthesis is indirect, based on coal gasification followed by FischerTropsch synthesis. Direct CTL is a significantly different process approach, but both indirect and direct coal liquefaction require water for the same reasons, from demands for process cooling, hydrogen demand, etc.
Since the late 1970s, coal liquefaction processes have been developed into integrated twostage processes, in which coal is liquefied in the presence of hydrogen in the first stage and the products are upgraded in the second stage.
The primary liquid emissions from coal conversion processes are heavily contaminated by ammonia, sulphides and other inorganics, as well as by phenolic and other organic compounds. The solid wastes are derived from coal ash, spent catalyst, and solid sludges. Previous chapter Next chapter 1. Introduction 62 2. Gasification 65
ash and sulphur content than the original coal. The SRCII process, however, was to produce distillate products; the distinguishing characteristic of the process was the recycle of vacuum bottoms. Two other direct coal liquefaction processes were under development in the USA at the same time: the Exxon Donor Solvent (EDS) process and the HCoal ...
Pyrite addition to a coal liquefaction process (22, 26) is controlled (118) in inverse proportion to the calcium content of the feed coal to maximize the F. ( C.) liquid yield per unit weight of pyrite added (110). The pyrite addition is controlled in this manner so as to minimize the amount of pyrite used and ...
One of several direct liquefaction processes currently under advanced stages of development is the SolventRefined CoalI (SRCI) process. A major SRC1 product option is a low sulfur, low ash solid (SRC) which could be used as an electric utility boiler fuel much in the same manner that pulverized coal is currently fired in this type of combustion equipment.
Coal liquefaction process employing fuel from a combined gasifier. Patent Schmid, B. Conversion of raw coal to distillate liquid and gaseous hydrocarbon products by solvent liquefaction in the presence of molecular hydrogen employing recycle of mineral residue is commonly performed at a higher thermal efficiency than conversion of coal to ...
Process. The Exxon donor solvent process is a noncatalytic processing of solventslurried coal in a highpressure liquefaction reactor. Coal is cleaned, crushed and fed to the slurry dryer, where water is removed. The dry crushed coal is slurried with the hydrogen donor recycle solvent. The coal slurry is treated with hydrogen and heated in a ...
[1] The indirect route is composed of 2 steps: First, coal is gasified with steam and oxygen to produce a synthesis gas (syngas), which is then cleaned to rid of dust, tar, and acid gases.
article{osti_, title = {Catalyst withdrawal and addition in a coal liquefaction process}, author = {Simone, A A and Ogren, D F}, abstractNote = {The catalyst is withdrawn from a coal hydroliquefaction reactor while it is maintained on stream by withdrawing a portion of the catalyst, in a separate stream, dispersed in product from the liquefaction zone, with such withdrawn stream being ...
1Historical background 2Methods Toggle Methods subsection and carbonization processes
coal liquefaction, any process of turning coal into liquid products resembling crude oil. The two procedures that have been most extensively evaluated are carbonization—heating coal in the absence of air—and hydrogenation—causing coal to react with hydrogen at high pressures, usually in the presence of a catalyst.
reported a twostage liquefaction process with Tanito Harum coal (Indonesian subbituminous coal) under the hydrogen pressure of 15 MPa using 10 wt% Fe10 wt% Ni catalyst supported on carbon nanoparticles. Under the optimal conditions of the two stage liquefaction: 380 °C for 15 min in the first stage and 450 °C for 105 min in the second ...
Therefore, while direct coal liquefaction (DCL) takes coal directly into a liquid phase, indirect coal liquefaction (ICL) consists of two major steps: (a) gasification to produce a synthesis gas (syngas); and (b) conversion of the carbon monoxide (CO) and hydrogen (H 2) in the syngas to a range of hydrocarbon fuels/products such as gasoline, die...
Direct coal liquefaction residue (DCLR) is, commonly, designed to be used as a feed stock for gasification or combustion. Use of DCLR as a value added product is very important for improving overall economy of direct coal liquefaction processes. This study shows that the DCLR may be used as a pavement asphalt modifier. The modification ability is similar to that of Trinidad Lake Asphalt (TLA ...
The direct coal liquefaction process usually produces a liquefaction residue of about 30% of its coal feed. The effective utilization of the coal liquefaction residue (CLR), which contains about 80% organic matter, is of great significance for improving the oil yield of the direct liquefaction process and reducing the amount of pollution emitted from this oilcontaining organic solid waste. In ...
Even though the process is currently not in use, it has contributed immensely to the development of catalytic coal liquefaction technology. The process involves the catalytic conversion of coal (slurried with heavy oil) in the presence of hydrogen and an iron oxide catalyst, at 450°C500°C and 200690 bars (197681 atm, or 2069 MPa).
The DCL process produces considerably highvariety and efficient products at low temperatures compared to the indirect coal liquefaction process. Generally, Fig. 1 shows the distinct difference between the direct and indirect liquefaction processes. Importantly, DCL consists of many steps for the conversion of coal to PA (preasphaltenes) and ...
4 Liquefaction. Coal liquefaction is the process of making a liquid fuel from coal. The fundamental difference between coal, a solid, and liquid fuels is that the liquid fuels have a higher hydrogen:carbon ratio. Liquid fuels have lower ash contents and are easier to upgrade (, to remove unwanted impurities such as nitrogen and sulfur). ...
Introduction. Direct coal liquefaction (DCL) is known as a clean and efficient coal utilization technology, in which solid coal could be converted into liquid fuels and high valueadded chemicals by hydrogenation. [ [1], [2], [3]] The Hdonor is an important index in DCL technology [ [4], [5], [6]]: It is considered as a medium for mass ...
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